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牌号简介 About |
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Aquivion® P87S-SO2F是以磺酰氟化物(-so2f)形式化学稳定(以S-后缀表示)的全氟化颗粒,其当量(ew)为870 g/eq。该材料基于Solvay生产的四氟乙烯(tfe)和磺酰氟化物乙烯基醚(sfve)f2c=cf-o-cf2cf2-so2f的独特短侧链共聚物。Aquivion® P87S-SO2F树脂可以很容易地熔化挤压成各种形状。挤出机应配备一个标准的三区计量螺杆,没有屏障或混合元件。最佳温度设置将取决于设备的配置,但一般在200至300°C之间。可选地,模制品中的功能组随后在浴槽或湿工作台中水解,加热的碱(NaOH、KOH等)反应可能需要几分钟或几小时,具体取决于厚度和条件。Aquivion® P87S-SO2F可按说明直接水解,完全或仅在其外表面上水解。这将使磺酸/磺酰盐基团在离子交换操作或作为酸催化剂时具有功能活性。与其他含氟聚合物一样,含水层PFSA颗粒在熔融物中具有腐蚀性;因此,所有与熔融物长期接触的零件均应采用耐腐蚀材料制成,如哈氏合金、铬镍铁合金、蒙乃尔合金或xaloy。不建议使用镀铬或镀镍,因为它们通常只足以进行短暂的加工试验。有关详细信息,请访问aquivion.com。 Aquivion® P87S-SO2F are chemically-stabilized (denoted by the S-suffix) perfluorinated pellets in the sulfonyl fluoride (-SO2F) form that exhibit an Equivalent Weight (EW) of 870 g/eq. This material is based on the unique Short Side Chain copolymer of Tetrafluoroethylene (TFE) and Sulfonyl Fluoride Vinyl Ether (SFVE) F2C=CF-O-CF2CF2-SO2F produced by Solvay. Aquivion® P87S-SO2F resin can be easily melt extruded into a variety of shapes. The extruder should be equipped with a standard three-zone metering screw devoid of barrier or mixing elements. Optimum temperature settings will depend on the configuration of the equipment, but generally range from 200 to 300°C. Optionally, functional groups in the molded part are then hydrolyzed in baths or wet benches with a heated base (NaOH, KOH etc) reaction which may take minutes or hours, depending on thickness and conditions. Aquivion® P87S-SO2F can be directly hydrolyzed as described, either completely or only on their outer surface. This will enable functional activity of the sulfonic acid / sulfonyl salt groups for ion-exchange operations or as an acid catalyst. Like other fluoropolymers, Aquivion PFSA pellets are corrosive in the melt; therefore, all parts having prolonged contact with the melt should be made with corrosion-resistant materials such as Hastelloy®, Inconel®, Monel® or Xaloy®. Chrome or nickel plating is not recommended since they are typically only sufficient for brief processing tests. Please visit Aquivion.com for more information. |
技术参数 Technical Data | |||
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物理性能 PHYSICAL |
额定值 Nominal Value |
单位 Units |
测试方法 Test Method |
熔体质量流动速率 Melt Flow Rate 2 |
ASTM D1238 | ||
270℃,2.16kg 270℃,2.16kg |
5.0 到 20 | g/10min | ASTM D1238 |
280℃,5.0kg 280℃,5.0kg |
15 到 50 | g/10min | ASTM D1238 |
当量 equivalent 3 |
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EW EW 3 |
840 到 900 | g/eq | 内部方法 |
密度 Density |
2.080 | g/cm³ | ASTM D792 |
热性能 THERMAL |
额定值 Nominal Value |
单位 Units |
测试方法 Test Method |
熔融温度 Melting temperature |
230 到 250 | ℃ | ASTM D3418 |
结晶热 Crystallization heat |
℃ | ASTM D3418 | |
融合热量 Fusion heat |
℃ | ASTM D3418 | |
补充信息 Supplementary information |
额定值 Nominal Value |
单位 Units |
测试方法 Test Method |
干燥时间 drying time |
hr | ||
Thermal Resistance Thermal Resistance 4 |
℃ | TGA | |
干燥温度 drying temperature |
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in vacuum oven in vacuum oven |
℃ |
备注 |
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1 一般属性:这些不能被视为规格。 |
2 Nominal value |
3 eq = mol SO3H |
4 In air, ramped 10°C/min |
【新闻资讯】查看全部
上半年化工原料及制品制造业利润增长16.4%
2022-08-03 7月27日,国家统计局公布的数据显示,上半年,规模以上工业企业实现利润总额42702.2亿元,同比增长1.0%。其中,化工原料及化工产品制造业利润总额4387.4亿元,同比增长16.4%。 数据显 |
【免责声明】 广州搜料信息技术有限公司保留所有权利。 此数据表中的信息由搜料网soliao.com从该材料的生产商处获得。搜料网soliao.com尽最大努力确保此数据的准确性。 但是搜料公司对这些数据值及建议等给用户带来的不确定因素和后果不承担任何责任,并强烈建议在最终选择材料前,就数据值与材料供应商进行验证。 |