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与Vamac G相比,杜邦Vamac® Ultra LT聚合物改善了低温性能。Vamac® Ultra LT 27聚合物的Tg比Vamac G的Tg低约12°C。由Vamac® Ultra LT制成的化合物与20 phr增塑剂的Tg为-54°C。不含增塑剂的化合物的Tg为-40°C,该化合物在空气中老化后保持Tg为-40°C。在150°C下6周或在175°C下1周。Vamac® Ultra LT种化合物的耐流体性不如g/gls化合物,但可以通过与vamac g混合来提高耐流体性。与g混合的混合物将具有中低温性能和中间耐流体性。聚合物通常用二胺固化。它也可以用过氧化物固化。橡胶弹性体具有低水平的加工助剂和1.03的名义比重。该聚合物具有温和的丙烯酸气味,且贮存稳定性好。由Vamac® Ultra LT制成的固化化合物具有良好的性能组合,包括适用于最终使用温度的宽操作窗口。不含增塑剂的化合物具有-40°C至165°C的温度窗口,并且该化合物能够承受高达200°C的短期温度峰值。通过添加增塑剂可以改善低温性能,并且对于20 phr增塑剂,初始Tg约为-54°C。固化化合物通常被评定为E级。对于使用ASTM D2000系统的耐热性,这意味着它们将在175°C(347°F)下通过70小时的额定热试验。它们还将在高达165°C(329°F)的温度下通过为期六周的空气老化要求。固化化合物的耐流体性取决于炭黑和增塑剂的含量。在150°C(302°F)下老化168小时后,IRM 903流体的体积膨胀的典型值约为90%。由Vamac® Ultra LT制成的化合物在变速器油和发动机机油中的体积膨胀要小得多。工作流体105(1周/150°C)中的体积膨胀约为50%,而ASTM 1(1周/150°C)中的体积膨胀约为7%。大多数新的发动机机油、变速器油和高温润滑脂比传统的测试油更合成,脂肪含量更高。新的液体也有更低或没有芳香含量。IRM903中的体积膨胀可能不是新流体性能的一个很好的预测因子。基于Vamac® Ultra LT的化合物的压缩设定值在150°C下一周后测量,其范围为20到40%。结果取决于疗效包装、炭黑含量和增塑剂含量。在Vamac® Ultra LT 27化合物上进行的CSR(压缩应力松弛)试验在150°C的机油中显示出非常好的性能,持续6周。保留密封力的百分比是一个相对较高的值,这可能是由于相对较高的体积膨胀。Vamac® Ultra LT化合物与vamac g化合物相比具有更高的值,与vamac gls化合物相比,vamac g化合物具有更高的保留密封力。Vamac® Ultra LT化合物的特性使其非常适合各种汽车应用,包括成型护套、动力总成密封件和垫圈、摇臂盖密封件、变速器油冷却液软管、动力转向软管、涡轮增压器软管、曲轴箱通风管、燃油和冷却液软管的覆盖物、O形圈、套圈和曲柄轴。后减振器。Vamac® Ultra LT是一种无卤聚合物,当暴露在火焰中时不会分解以释放腐蚀性气体。可用于阻燃、低烟、无卤电线电缆护套及无卤、低烟地板。Vamac® Ultra LT化合物非常适合于注射、转移或压缩成型。它们也可以被挤压。 DuPont™ Vamac® Ultra LT polymer has improved low-temperature properties compared to Vamac® G. The Tg for Vamac® Ultra LT polymer is about 12°C lower than the Tg for Vamac® G. A compound made from Vamac® Ultra LT with 20 phr of plasticizer has a Tg of -54°C. A compound without any plasticizer has a Tg of -40°C and that compound maintains that Tg after aging in air for six weeks at 150°C or for one week at 175°C. The fluid resistance of Vamac® Ultra LT compounds is not as good as the G/GLS compounds, but resistance can be improved by blending with Vamac® G. The blends with G will have intermediate low-temperature performance and intermediate fluid resistance. The polymer is typically cured with a diamine. It can also be cured with a peroxide. The gum elastomer has a low level of a processing aid and a nominal specific gravity of 1.03. The polymer has a mild acrylic odor and the storage stability of the polymer is excellent. Cured compounds made from Vamac® Ultra LT have a good combination of properties including a wide operating window for end use temperatures. A compound with no plasticizer has a temperature window of -40°C up to 165°C and the compound can withstand short term temperature spikes up to 200°C. The low temperature properties can be improved by the addition of a plasticizer, and with 20 phr of plasticizer the initial Tg is about -54°C. The cured compounds are typically rated as class E for heat resistance using the ASTM D2000 system and this means that they will pass a heat rating test of 70 hours at 175°C (347°F). They will also pass a six week air aging requirement at temperatures as high as 165°C (329°F). The fluid resistance of a cured compound depends on the carbon black and plasticizer level. A typical value for volume swell in IRM 903 fluid after aging for 168 hr at 150°C (302°F) is about 90%. The compounds made from Vamac® Ultra LT have much lower volume swell in transmission fluid and in engine oils. The volume swell in Service Fluid 105 (1 week/150°C) is about 50% and the volume swell in ASTM #1 (1 week/150°C) is about 7%. Most of the newer engine oils, transmission fluids, and high temperature greases are more synthetic and have higher aliphatic content than conventional test oils. The newer fluids also have much lower or no aromatic content. The volume swell in IRM903 may not be a good predictor for performance in the newer fluids. The compression set values for compounds based on Vamac® Ultra LT were measured after one week at 150°C and the range in values is from 20 to 40%. The results depend on the curative package, the level of carbon black and the level of plasticizer. CSR (Compressive Stress Relaxation) tests run on Vamac® Ultra LT compounds exhibit very good properties for six weeks at 150°C in engine oils. The percent retained sealing force is a relatively high value and this is probably due to the relatively high volume swell. The Vamac® Ultra LT compounds have higher values compared to the Vamac® G compounds which in turn have higher retained sealing forces compared to Vamac® GLS compounds. The properties of Vamac® Ultra LT compounds make them well suited for a wide range of automotive applications, including, molded boots, powertrain seals and gaskets, rocker cover seals, transmission oil coolant hoses, power steering hoses, turbocharger hoses, crankcase ventilating tubes, coverings for fuel and coolant hoses, O-rings, grommets and crankshaft dampers. Vamac® Ultra LT is a halogen free polymer and does not decompose to give off corrosive gases when exposed to flame. It can be used for flame retardant, low-smoke, non-halogen wire and cable jackets and in non-halogen, low smoke flooring. Vamac® Ultra LT compounds are well suited for injection, transfer or compression molding. They also can be extruded. |
技术参数 Technical Data | |||
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物理性能 PHYSICAL |
额定值 Nominal Value |
单位 Units |
测试方法 Test Method |
门尼粘度 Mooney viscosity |
ASTM D1646 | ||
121℃ 121℃ 2 |
8 | MU | ASTM D1646 |
121℃ 121℃ |
12 | MU | ASTM D1646 |
ML 1+4,100℃ ML 1+4,100℃ 3 |
11 | MU | ASTM D1646 |
ML 1+4,100℃ ML 1+4,100℃ 2 |
23 | MU | ASTM D1646 |
ML 1+4,100℃ ML 1+4,100℃ |
37 | MU | ASTM D1646 |
机械性能 MECHANICAL |
额定值 Nominal Value |
单位 Units |
测试方法 Test Method |
邵氏硬度 Shore hardness |
ASTM D2240 | ||
邵氏 A Shaw's A 2 |
ASTM D2240 | ||
邵氏 A Shaw's A |
ASTM D2240 | ||
弹性体 elastic body |
额定值 Nominal Value |
单位 Units |
测试方法 Test Method |
拉伸强度 tensile strength |
ASTM D412 | ||
100% 应变 100% strain 2 |
MPa | ASTM D412 | |
屈服 yield 2 |
MPa | ASTM D412 | |
屈服 yield |
MPa | ASTM D412 | |
拉伸应变 Tensile strain 2 |
|||
断裂 fracture 2 |
% | ASTM D412 | |
撕裂强度 tear strength 4 |
ASTM D624 | ||
-- -- 2 |
kN/m | ASTM D624 | |
-- -- |
kN/m | ASTM D624 | |
压缩形变 Compression deformation |
ASTM D395 | ||
150℃,70 hr 150℃,70 hr 2 |
% | ASTM D395 | |
150℃,70 hr 150℃,70 hr |
% | ASTM D395 | |
150℃,138 hr 150℃,138 hr |
% | ASTM D395 | |
150℃,168 hr 150℃,168 hr 2 |
% | ASTM D395 | |
老化性能 Aging performance |
额定值 Nominal Value |
单位 Units |
测试方法 Test Method |
Change in Glass Transition Temperature Change in Glass Transition Temperature |
|||
-- -- 5 |
℃ | ASTM D471 | |
-- -- 6 |
℃ | ASTM D471 | |
-- -- 7 |
℃ | ASTM D471 | |
-- -- 8 |
℃ | ASTM D471 | |
150℃ 150℃ 9 |
℃ | ASTM D573 | |
150℃ 150℃ 10 |
℃ | ASTM D573 | |
175℃ 175℃ 11 |
℃ | ASTM D573 | |
175℃ 175℃ 12 |
℃ | ASTM D573 | |
热性能 THERMAL |
额定值 Nominal Value |
单位 Units |
测试方法 Test Method |
玻璃化转变温度 Glass transition temperature |
ASTM D3418 | ||
-- -- 2 |
℃ | ASTM D3418 | |
-- -- |
℃ | ASTM D3418 | |
玻璃化转变温度 Glass transition temperature |
ASTM D3418 | ||
DMA Results - dan delta DMA Results - dan delta 13 |
℃ | ASTM D3418 | |
DMA Results - dan delta DMA Results - dan delta 14 |
℃ | ASTM D3418 | |
DMA结果 - 损耗模数 DMA result - loss modulus 13 |
℃ | ASTM D3418 | |
DMA结果 - 损耗模数 DMA result - loss modulus 14 |
℃ | ASTM D3418 | |
静态O形圈测试 Static O-ring testing 13 |
℃ | ASTM D3418 | |
静态O形圈测试 Static O-ring testing 14 |
℃ | ASTM D3418 | |
TR10 TR10 |
℃ | ASTM D3418 | |
TR10 TR10 2 |
℃ | ASTM D3418 | |
TR30 TR30 2 |
℃ | ASTM D3418 | |
TR30 TR30 |
℃ | ASTM D3418 | |
补充信息 Supplementary information |
额定值 Nominal Value |
单位 Units |
测试方法 Test Method |
MDR MDR |
ASTM D5289 | ||
MH:177℃ MH:177℃ 15 |
dNm | ASTM D5289 | |
MH:177℃ MH:177℃ 16 |
dNm | ASTM D5289 | |
ML:177℃ ML:177℃ 15 |
dNm | ASTM D5289 | |
ML:177℃ ML:177℃ 16 |
dNm | ASTM D5289 | |
t50:177℃ t50:177℃ 15 |
min | ASTM D5289 | |
t50:177℃ t50:177℃ 16 |
min | ASTM D5289 | |
t90:177℃ t90:177℃ 15 |
min | ASTM D5289 | |
t90:177℃ t90:177℃ 16 |
min | ASTM D5289 | |
ts2:177℃ ts2:177℃ 16 |
min | ASTM D5289 | |
ts2:177℃ ts2:177℃ 15 |
min | ASTM D5289 | |
Mooney Scorch Mooney Scorch |
ASTM D1646 | ||
t10:121℃ t10:121℃ |
min | ASTM D1646 | |
t10:121℃ t10:121℃ 2 |
min | ASTM D1646 | |
t3 t3 2 |
min | ASTM D1646 | |
t3:121℃ t3:121℃ |
min | ASTM D1646 | |
挥发性 volatility |
wt% | 内部方法 |
备注 |
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1 一般属性:这些不能被视为规格。 |
2 20 phr plasticizer |
3 Target |
4 C 模具 |
5 1 Hz |
6 20 phr plasticizer, 1 Hz |
7 after 1 week in SF105, 20 phr plasticizer |
8 after 1 week in ASTM #1 |
9 after 1 week in ASTM #1, 20 phr plasticizer |
10 after 1 week in SF105 |
11 after Air Aging, 6 weeks |
12 after Air Aging, 6 weeks, 20 phr plasticizer |
13 after Air Aging, 1 week, 20 phr plasticizer |
14 after Air Aging, 1 week |
15 20 mins/0.5 degree arc, 20 phr plasticizer |
16 20 mins/0.5 degree arc |
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